Prereq steps:
More info on User Profile Synchronization service:
http://technet.microsoft.com/en-us/library/ee721049.aspx
To add your SharePoint server to the AD RMS Certification Pipeline
10. Click Start, and then click Command Prompt.
11. Type iisreset, and then press ENTER.
Once the AD RMS cluster certification pipeline has been allowed so that SPS-SRV can communicate with it, you must configure SharePoint Server to use the AD RMS cluster:
To enable Information Rights Management in Office SharePoint Server