Hi YaYaTech123,
According to your description, I understand that you want to activate SFB 2016 client, for this issue you could use office customization tool to activate SFB client, for details, please refer to the following similar case
https://social.technet.microsoft.com/Forums/ie/en-US/78cc5202-f2d7-4471-9533-0ff7c3d6df9d/activating-the-skype-for-business-2016-client?forum=sfbfr
Note: Although the screenshots are for Lync 2013 client, but the same for Skype for Business 2016. This deployment is not meant for any Office 365 or Click-to-run product
If you want to use SCCM to activate SFB client, we suggest you post in SCCM forum, there are more experts will help you resolve this issue, thanks for your understanding and support.
https://social.technet.microsoft.com/Forums/en-US/home?category=systemcenter2012configurationmanager
Regards,
Alice Wang
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