Word crashes when printing? Not to get too picky but Word doesn't print, the operating system prints.
If the definition of "crash" is that Word and/or the system appears to lock up after clicking on print, the problem is most likely an embedded object in the document that the print driver can't handle during the handoff.
I'd start looking carefully at the document in Print Previw and see if you can spot a place where something appears "missing" such as a graphic, image, chart, etc. If you can't spot it there then do a binary search method. Divide the document in half
and find out which half has the problem. Then keep dividing the problem half until you find the problem object.
Kind Regards, Rich ... http://greatcirclelearning.com