With the correct syntax you'll get the expected results ... ;-)
Get-PSDrive -PSProvider FileSystem |
Select-Object -Property Name,
Root,
@{Name = 'Used'; Expression = { "{0:N0}" -f $_.Used}},
@{Name = 'Free'; Expression = { "{0:N0}" -f $_.Free}},
Description |
Format-Table -AutoSize
But you should keep in mind that these numbers are actually not numbers anymore ... you couldn't calculate with them - they're strings.
Best regards,
(79,108,97,102|%{[char]$_})-join''