Hi Lyncer2013,
As the certificate is issued by internal CA, you need to download, copy and install it in external client. Here's a link about different type of certificate:
https://technet.microsoft.com/en-us/library/dd351044(v=exchg.160).aspx
Reference link about S/MIME:
S/MIME for message signing and encryption
Set up virtual certificate collection to validate
S/MIME
Regards,
Kelvin Deng
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