Dear Vinod,
Please check the Google official help article for how to:
Configure SAML single sign-on for Chrome devices
https://support.google.com/chrome/a/answer/6060880?hl=en
Besides, check this similar case for a hint:
SSO Not Working with Edge or Chrome
Chrome does not play well with AD or SSO unless you have the Google ADM/ ADMX solutions.
Google does have a paid solution, but part of my role is to keep it cheap
https://community.spiceworks.com/topic/2181497-sso-not-working-with-edge-or-chrome
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Regards
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