A common request from Microsoft User Experience Virtualization (UE-V) customers is the ability to synchronize settings via SkyDrive or SkyDrive Pro.  UE-V does not currently support this configuration.
While it is technically possible to use your %homepath%\SkyDrive or %homepath%\SkyDrive@Company folder to store UE-V settings by configuring the UE-V Settings Storage Path, UE-V cannot guarantee a transactional copy of the settings package and the external files that are associated with it.